THE SIGNIFICANCE OF HALIDE IN GRIGNARD REAGENTS
نویسندگان
چکیده
منابع مشابه
Di-Grignard reagents and metallacycles
Aliphatic ,w-dibromides can be converted to the corresponding c,w-di—Grignard reagents; for those members carrying less than four carbon atoms between the functions, special procedures are required. The synthesis, structure and applications of the di-Grignard reagents are discussed; particular emphasis is placed on the structures of the corresponding cyclic dialkylmagnesiums, and on the use of ...
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The preparation of silylamide Hauser base (R2NMgX; X = halide) and amido-Grignard (R2NMgR) complexes from simple Grignard reagents using [K{N(SiMe2 Bu)2}]n, [K{N(SiMe2 Bu)(SiPr3)}]n and [K{N(Si Pr3)2}]n, and their parent silylamines, was explored. Both salt metathesis and protonolysis routes proved ineffective with allylmagnesium chloride as a starting material due to complex Schlenk equilibria...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1964
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v64-363